The Curve Representing Electrical Double Layer Capacity against Electrode Potential of Fe-HClO4 System Containing Organic Acids

Time-dependent electrical double layer with blocking electrode

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Exact analytical expressions for the potential of electrical double layer interactions for a sphere-plate system.

Exact, closed-form analytical expressions are presented for evaluating the potential energy of electrical double layer (EDL) interactions between a sphere and an infinite flat plate for three different types of interactions: constant potential, constant charge, and an intermediate case as given by the linear superposition approximation (LSA). By taking advantage of the simpler sphere-plate geom...

Electrical Double Layer

Differential Capacity of the Double-Layer Formed at a Solid Electrode (Pt, Au)/Ionic Liquid Interface

Salts of low melting points, usually called ionic liquids (ILs), have been studied extensively during the last decade [1 – 3]. These liquid salts may serve as solvents for chemical reactions as well as electrolytes in electrochemical devices. The first extensively studied IL was 1-ethyl-3-methyl-imidazolium tetrachloroaluminate ([EMIm][AlCl4]). However such ionic liquids containing AlCl4− are e...

Two tributaries of the electrical double layer.

This special issue of Journal of Physics: Condensed Matter focuses on physical aspects of capacitive energy storage and harvesting devices based on electrical double layers. An electrical double layer (EDL) is an interfacial structure in which charges are separated between two neighboring phases or layers. Originally introduced by Helmholtz in 1850, the concept of EDLs has found numerous applic...